rotational constant of co

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��G��}�� _�2�nq��X3� ��[��8�dy��I,)� ��z��#"��1� �` ��Y� endstream endobj 110 0 obj 569 endobj 111 0 obj << /Filter /FlateDecode /Length 110 0 R >> stream 0000019473 00000 n The ADS is operated by the Smithsonian Astrophysical Observatory under NASA Cooperative Notice, Smithsonian Terms of 1979) was used to calculate the rotational energy levels. There is no implementation of any of the finer points at this stage; these include nuclear spin statistics, centrifugal distortion and anharmonicity. The rotational constant of CO is 1.931 cm1. Jones and Gordy (13) have reported measurements for CO up to the 5 --+ 6 rotational transition. Hey! The vibrational constants in vacuum wave numbers are: W e = 2169.8232, W e X e = -13.2932, W e Y e = 0.01144. 0000015889 00000 n Molecular spectroscopists define the rotational constant B which has which as units of energy. 0000013638 00000 n The first rotational line in the rotational spectrum of CO is observed at 3.84235 cm-1. We can compare the Evaluate the rotational partition function (without approximation) at temperature T=10 K by direct summation over the first 10 terms and compare the obtained value with partition function The rotational constant for CO is 1.9314 cm −1 and 1.6116 cm −1 in the ground and first excited vibrational states, respectively. 0000005070 00000 n The rotational constants are: B0 = 1.922 521, D0 = −6.1193 × 10 −6, H 0 = 5.8 × 10 −12, αe = −0.017507, βe = 1.0 × 10 −9, γe = 1.0 × 10 −6. ; B = rotational constant, units cm-1 4. O/L�ew`@G��:�n�r�.�b�*��W�[�B��;Ӣ8�X̢ 0000008043 00000 n is the Boltzmann constant. See section I.F.4 to change rotational constant units A B C reference comment 0.39021 1966Herzberg Calculated rotational constants for CO 2 (Carbon dioxide). Determining the rotational constant B enables you to calculate the bond length R. The allowed transitions for the diatomic molecule are regularly spaced at interval 2B. 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